2-(Tritylsulfanyl)ethyl 3-iodobenzoate
نویسندگان
چکیده
The triphenyl-methyl group in the title compound, C(28)H(23)IO(2)S, has the methine carbon slightly flattened out [ΣC(phen-yl)-C-C(phen-yl) = 332.8 (6) °]. The -C-O-C-C-S- chain connecting the triphenyl-methyl group and the aromatic ring adopts an extended zigzag conformation, these five atoms being approximately co-planar (r.m.s. deviation 0.260 Å).
منابع مشابه
2-(Tritylsulfanyl)ethyl 2-iodobenzoate
The methine C atom of the triphenyl-methyl group in the title compound, C(28)H(23)IO(2)S, is slightly flattened out [ΣC(phen-yl)-C-C(phen-yl) = 335.6 (5)°]. The -C-O-C-C-S- chain connecting the triphenyl-methyl group and the aromatic ring adopts an extended zigzag conformation, these five atoms lying on an approximate plane (r.m.s. deviation = 0.120 Å).
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The title compound, C(44)H(35)NS, is a derivative of amino-thio-phenol and possesses a protected S-triphenyl-methyl thio-ether and an N-triphenyl-methyl-amine functional group. The trityl groups show an anti orientation, with C-C-N-C and C-C-S-C torsion angles of -151.0 (3) and -105.3 (2)°, respectively. There is an intra-molecular N-H⋯S hydrogen bond.
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